浅谈水质中氟化物的分析方法

经过长期的工作实践，笔者总结出能够大大提高水中氟化物测定效率及准确度的操作方法。即在使用离子选择电极法测量水中氟化物时，首先要保证试验用的去离子水的纯净度，同时确保电极清洗到260mv以上，再开始试验，最后在绘制标准曲线时保证斜率的绝对值在（58±1）之间。     

构建湘江流域生态补偿机制的探讨

本文以湘江水质和水文数据为基础,首次结合各地市社会经济发展情况,引入补偿标准系数,以湘江流域所在区域为例进行生态补偿资金测算,提出湘江流域生态补偿机制构建初步设想和存在的主要问题,以期为湘江流域水资源保护提供指导,最终实现湘江流域区域共赢。     

资源所在地的利益补偿机制初探——以油气田资源开发为例

油气资源作为战略性资源，关系到经济发展、社会稳定、国家安全和全面建设小康社会目标的顺利实现。资源所在地为国家建设输出了大量的能源，本地的经济发展却依然处于落后状况，导致目前资源所在地出现了种种矛盾和冲突。究其原因，主要是缺乏对资源所在地的利益补偿机制所致。以油气田资源开发的利益分配现状为例，指出目前的利益分配中主要存在资源所在地税收分配收益少、开发带来的生态污染补偿缺失、油气田项目征地补偿过低、资源开发没有促进资源所在地的经济发展等问题，从福利经济学、公共政策管理的相关理论提出了构建利益补偿机制的理论依据，并在此基础上提出了收益向资源所在地倾斜、实行生态补偿、创新征地补偿方式和资源就地转化的政策建议。     

生态补水对玄武湖水质的影响

分析南京玄武湖1997年-2010年的水质变化，以及生态补水与玄武湖水质变化的关系。结果表明，玄武湖于1998年实施生态补水，随着生态补水的持续运行和生态补水量的不断增加，玄武湖水质得以显著改善，其水质类别由生态补水前的劣V类水体转为V类水体，并接近于Ⅳ类水体，富营养化程度由重度富营养化水平转为轻度富营养化水平。目前玄武湖主要营养物质来源于生态补水，相关性分析显示各湖区TN浓度与生态补水中TN浓度呈显著相关关系。     

广州PM2.5污染特征及影响因素分析

对广州市2008—2010年PM_2.5质量浓度、影响因素数据资料进行整理统计,通过定性分析、定量计算以及对各物理量之间的相互作用过程研究,得出PM_2.5质量浓度变化特征和各影响因素之间的关系。结果表明,PM_2.5质量浓度变化呈现夏季和非夏季2种典型的季节性特征,夏季月平均值0.049 mg/m³,主要分布在0.03～0.05 mg/m³,非夏季月均值为0.063 mg/m³,分布于0.05～0.08 mg/m³之间;夏季、非夏季PM_2.5质量浓度超标率(采用美国EPA标准)分别为70.7%、77.8%,质量标准2倍、3倍以上出现的概率都表现出明显的季节性差异;PM_2.5与温度正相关,和其他因素负相关,其中与能见度相关性最大,其次是温度、风速,与降雨量相关性最差,与气压、相对湿度相关系数季节性特征显著。     

Mercury levels and trends (1993-2009) in bream (Abramis brama L.) and zebra mussels (Dreissena polymorpha) from German surface waters

Mercury concentrations have been analysed in bream (Abramis brama L.) and zebra mussels (Dreissena polymorpha) collected at 17 freshwater sites in Germany from 1993-2009 and 1994-2009, respectively, within the German Environmental Specimen programme. Mercury concentrations in bream ranged from 21 to 881 ng g⁻¹ wet weight with lowest concentrations found at the reference site Lake Belau and highest in fish from the river Elbe and its tributaries. Statistical analysis revealed site-specific differences and significant decreasing temporal trends in mercury concentrations at most of the sampling sites. The decrease in mercury levels in bream was most pronounced in fish from the river Elbe and its tributary Mulde, while in fish from the river Saale mercury levels increased. Temporal trends seem to level off in recent years. Mercury concentrations in zebra mussels were much lower than those in bream according to their lower trophic position and varied by one order of magnitude from 4.1 to 42 ng g⁻¹ wet weight (33-336 ng g⁻¹ dry weight). For zebra mussels, trend analyses were performed for seven sampling sites at the rivers Saar and Elbe of which three showed significant downward trends. There was a significant correlation of the geometric mean concentrations in bream and zebra mussel over the entire study period at each sampling site (Pearson’s correlation coefficient = 0.892, p = 0.00002). A comparison of the concentrations in bream with the environmental quality standard (EQS) of 20 ng g⁻¹ wet weight set for mercury in biota by the EU showed that not a single result was in compliance with this limit value, not even those from the reference site. Current mercury levels in bream from German rivers exceed the EQS by a factor 4.5-20. Thus, piscivorous top predators are still at risk of secondary poisoning by mercury exposure via the food chain. It was suggested focusing monitoring of mercury in forage fish (trophic level 3 or 4) for compliance checking with the EQS for biota and considering the age dependency of mercury concentrations in fish in the monitoring strategy.     

不同模糊评价方法在水环境质量评价中的应用比较

近年来,运用模糊评价方法对水质和水体营养化程度进行评价逐渐受到重视。目前,对模糊评价方法的研究多集中在实测数据标准化、权重的确定和模糊模式识别模型研究几个方面。以滇池历年营养物质数据为实测数据,通过对几种实测数据标准化方法、权重确定方法和模糊模式识别方法的组合应用,获得水环境质量模糊评价最优组合方法。结果表明,在评价方法中,实测数据标准化方法采用线性内插法,权重的确定采用超标倍数法,模糊模式识别模型采用广义海明距离和加权海明距离法,即采用超标倍数法的广义海明距离和加权海明距离法能够更真实反映水环境质量的实际情况。     

有害物质环境测试组合舱的研制及性能评价

研制了一种新型有害物质环境测试组合舱,该测试舱由舱体系（内舱和外舱）、恒温恒湿空气处理系统、空气循环装置和信号控制与处理软件组成。该测试舱具有可分别使用内舱和外舱对样品进行测试的特点,并采用美国FLUNT公司开发的air pack软件包对内舱和外舱的气流进行模拟与计算,并划分出内舱的层流区域,同时也对舱体系的性能进行了测试与评价。结果表明,有害物质环境测试组合舱的温湿度的相对标准偏差分别为0.04℃和0.7%,混合性达到90.7%。因此,该有害物质环境测试组合舱对温湿度控制精准,气流稳定,混合性能良好,能为室内空气污染研究提供条件稳定的室内仿真环境。     

北京市开展区域水环境合作探究

通过分析北京市地表水资源、水环境质量现状及存在的问题，得出生态环境用水严重短缺是制约北京市水环境质量全面改善的根本原因，并对此提出全面加强区域水环境合作、改善北京市水环境的基本思路，及与周边地区开展水环境合作的途径及建议。     

Economic sustainability and the preservation of environmental assets

The core requirement of sustainability is that current economic activities should not result in an excessive burden on future generations. This criterion is general enough to imply different decision rules for the preservation of environmental assets. Neoclassical economics does not have a sustainability criterion for environmental assets independent of the intertemporal efficiency criterion, which allocates environmental and man-made capital based on projected monetary benefits and costs. This criterion is examined in terms of the feasibility of valuing the benefits of environmental assets, the substitution possibilities between natural and man-made capital, and the ethical grounds for using efficiency as the sole determinant of the allocation of environmental assets. An alternative ecological sustainability criterion is the preservation of safe minimum levels of environmental assets in physical terms rather than the dollar value of a composite of natural and man-made capital. Safe minimum standards for environmental assets constrain the efficiency criterion in order to ensure the sustainability of economic systems. It is argued that the ecological approach to sustainability should limit the economic approach for decisions involving the allocation of environmental assets.